段圣国

一、个人简介

段圣国，副教授，硕士生导师。2011年本科毕业于山东大学，药学专业。2018年博士毕业于兰州大学，有机化学专业。主持国家级基金项目一项，省部级基金项目一项。第一作者或通讯作者发表论文11篇。

实验室：重点实验室313。

电话：19857111664（微信同号）。

邮箱：duanshg@hbu.edu.cn

二、主讲课程及研究方向

1.主讲课程：有机化学，有机化学实验

2.研究方向：有机合成方法学，天然产物全合成

三、已发表论文

(27) Huaping Xu, Heng Wang, Ze-Feng Xu,*Shengguo Duan, and Chuan-Ying Li*. Synthesis of Cyclopenta[b]indoles via Rhodium-Catalyzed Cascade Migration-Annulation of 1-Sulfonyl-1,2,3-triazoles and Indoles,Advanced Synthesis & Catalysis,2023,365, 1623 – 1628.

(26) Tao Tang, Jing Chen, Ze-Feng Xu,Shengguo Duan,*and Chuan-Ying Li*. Iodine- and Bromine-Promoted Transformations of Pyridotriazoles: General Access to Geminal Diiodo and Dibromo Methylpyridines,Asian Journal of Organic Chemistry,2023,12, e202300026.

(25) Huaping Xu, Xiaoyu Kong, Mengjie Cen, Ze-Feng Xu,*Shengguo Duan, and Chuan-Ying Li*. 1,3-Sulfinate Migration Triggered by α-Imino Carbene and Divergent Zwitterion Cyclization: Synthesis of Cyclopropane, Dihydropyrrole, and Azepane Ring Systems,European Journal of Organic Chemistry,2023,26, e202201417.

(24) Yuchen Jie, Huiqin Hu, Ze-Feng Xu,Shengguo Duan*, and Chuan-Ying Li*. Synthesis of 3-Methylidene-2,3-dihydropyrroles via Formal 1,2-Enamine Migration/Cyclization Cascade of Rhodium Carbenes,Advanced Synthesis & Catalysis,2023,365, 161 – 166.

(23) Huaping Xu, Xiaoyu Kong, Mengjie Cen, Ze-Feng Xu*,Shengguo Duan, and Chuan-Ying Li*. Synthesis of dihydropyrroles fromin situ-generated zwitterionsviaRh₂(adc)₄/TBAI dual catalysis,Chemical Communications,2022,58, 12244 – 12247.

(22) Zijuan Feng, Hongjian Jiao, Zihang Ye, Jie Ye, Ze-Feng Xu*,Shengguo Duan, and Chuan-Ying Li*. Synthesis of Azepane Derivatives via Formal 1,3-Migration of Hydroxy and Acyloxy Groups and Selective Annulation,Organic Letters,2022,24, 5254 – 5259.

(21) Zijuan Feng, Weipeng Wang, Zhenxing Yan, Xiaojing Xu,Shengguo Duan, Ze-Feng Xu*, Chao Deng*, and Chuan-Ying Li*. Synthesis of α-Amino Cyclobutanones via Formal 1,3-Hydroxy Migration Triggered by Formation of α-Imino Rhodium Carbene,Organic Letters,2022,24, 2950 – 2954.

(20)Cong Chen, Hongjian Jiao, Di Chen, Tao Tang, Ze-Feng Xu,Shengguo Duan*, and Chuan-Ying Li*. Access to tetrahydrocarbazoles and pyrrolo[3,4-b]carbazoles through sequential reactions of triazoles and indoles,Organic & Biomolecular Chemistry,2022,20, 2802 – 2807.

(19)Shengguo Duan, Cong Chen, Yidian Chen, Yuchen Jie, Huan Luo, Ze-Feng Xu, Bin Cheng, and Chuan-Ying Li*. Two Reaction Modes of 1-Sulfonyl-1,2,3-triazoles and Pyridinium 1,4-Zwitterionic Thiolates: Catalyst-Free Synthesis of Pyrido[1,2-a]pyrazine Derivatives and 1,4-Thiazine Derivatives,Organic Chemistry Frontiers,2021,8, 6962 – 6967.

(18) Tao Chen, Zhenxing Yan,Shengguo Duan, Ze-Feng Xu*, and Chuan-Ying Li*. Grob-type fragmentation of an oxonium ylide generated from α-imino rhodium carbene,Organic Chemistry Frontiers,2021,8, 6371 – 6376.

(17)Shengguo Duan*, Qiaoyi Xiang, Changchang Deng, Yuchen Jie, Huan Luo, and Ze-Feng Xu. Synthesis of phthalan derivatives via a formal intramolecular 1,3-insertion of rhodium(II) azavinyl carbenes into O-Si bond,Tetrahedron Letters,2021,80, 153329.

(16) Saygbechi T. Jablasone, Jr, Zihang Ye,Shengguo Duan, Ze-Feng Xu*, and Chuan-Ying Li*. Synthesis of benzothiazonine by rhodium-catalyzed denitrogenative transannulation of 1-sulfonyl-1,2,3-triazole and thiochromone,Organic & Biomolecular Chemistry,2021,19, 5758 – 5761.

(15)Shengguo Duan, Bing Xue, Hui Meng, Zihang Ye, Ze-Feng Xu, and Chuan-Ying Li*. Rhodium(II)-Catalyzed [4+3] Cyclization of Triazoles with Indole Derivatives and Its Application in the Total Synthesis of (±)-Aurantioclavine,Chinese Journal of Chemistry,2021,39, 1145-1152.

(14)Shengguo Duan, Hui Meng, Saygbechi T. Jablasone, Jr., Huan Luo, Ze-Feng Xu, and Chuan-Ying Li*. Rhodium(II)-Catalyzed [4+2] Annulation of Ester-Tethered 1-Sulfonyl-1,2,3-Triazoles and Hexahydro-1,3,5-Triazines,Asian Journal of Organic Chemistry,2021,10, 1076-1080.

(13)Shengguo Duan, Yidian Chen, Hui Meng, Lihong Shan, Ze-Feng Xu, and Chuan-Ying Li*. Synthesis of [1,2,3]-Triazolo[5,1-a]-isoquinolines through TBAF-Promoted Cascade Reactions,Asian Journal of Organic Chemistry,2021,10, 224-232.

(12)徐泽锋，段圣国，李传莹．浅谈学生综合思维能力的培养——以Favorskii重排为例[J]．广东化工，2020，47(20)：172-173。

(11) Bin Cheng*, Hui Li^‡,Shengguo Duan^‡, Xinping Zhang, Yixuan He, Yuntong Li, Yun Li, Taimin Wang*, and Hongbin Zhai*. Synthesis of indolizines from pyridinium 1,4-zwitterionic thiolates and propiolic acid derivatives via a formal [4+1] pathway,Organic & Biomolecular Chemistry,2020,18, 6253 – 6257.

(10) Bin Cheng*, Yuntong Li, Xinping Zhang,Shengguo Duan, Hui Li, Yixuan He, Yun Li, Taimin Wang*, and Hongbin Zhai*. Two Reaction Modes of Pyridinium 1,4-Zwitterionic Thiolates with Sulfenes: Synthesis of 3H-1,2-Dithiole 2,2-Dioxides, 1,9a-Dihydropyrido[2,1-c][1,4]thiazines, and Indolizines,Organic Letters,2020,22, 5817 – 5821.

(9)Shengguo Duan, Wan Zhang, Yuntong Hu, Ze-Feng Xu, and Chuan-Ying Li*. Synthesis of Cyclopenta[b]indoles via a Formal [3+2] Cyclization ofN-Sulfonyl-1,2,3-triazoles and Indoles,Advanced Synthesis & Catalysis,2020,362, 3570-3575.

(8) Ze-Feng Xu*, Jincheng Liu, Xin Chang, Tao Chen, Huaping Xu,Shengguo Duan, and Chuan-Ying Li*. Synthesis of Cyclopropanes via 1,3-Migration of Acyloxy Groups Triggered by Formation of α-Imino Rhodium Carbenes,Organic Letters,2020,22, 5163 – 5169.

(7) Ze-Feng Xu*, Weipeng Wang, Mengjie Cen, Zijuan Feng,Shengguo Duan, and Chuan-Ying Li*. Synthesis of α-(2-Hydroxyphenyl)-α-Aminoketones by Rhodium-Catalyzed Tandem Reaction of 1-Sulfonyl-1,2,3-Triazoles and Benzoquinone-Derived Alcohols,Advanced Synthesis & Catalysis,2020,362, 2888 – 2893.

(6)Shengguo Duan, Yuehui An, Bing Xue, Yidian Chen, Wan Zhang, Ze-Feng Xu, and Chuan-Ying Li*. Synthesis of Pyrido[2,3-b]indole Derivatives via Rhodium-Catalyzed Cyclization of Indoles and 1-Sulfonyl-1,2,3-triazoles,Advanced Synthesis & Catalysis,2020,362, 1831 – 1835.

(5) Mengjie Cen, Qiaoyi Xiang, Yiwen Xu,Shengguo Duan, Yaohong Lv, Ze-Feng Xu*, and Chuan-Ying Li*. Synthesis of α-cyano sulfone via thermal rearrangement of 1,4-disubstituted triazole mediated by carbene and radical species,Organic Chemistry Frontiers,2020,7, 596 – 601.

(4) Ze-Feng Xu*, Yuehui An, Yidian Chen, andShengguo Duan. Rhodium-catalysed synthesis of fused pyrimidine derivatives employingN-sulfonyl-1,2,3-triazoles as a 1-aza-[4C] synthon,Tetrahedron Letters,2019,60, 1849 – 1853.

(3)Shengguo Duan, Bin Cheng*, Xiaoguang Duan, Bian Bao, Yun Li, and Hongbin Zhai*. Synthesis of cis-5,5a,6,10b-Tetrahydroindeno[2,1-b]indoles through Palladium-Catalyzed Decarboxylative Coupling of Vinyl Benzoxazinanones with Arynes,Organic Letters,2018,20, 1417 – 1420.

(2) Bin Cheng*, Bian Bao, Bing Zu, Xiaoguang Duan,Shengguo Duan, Yun Li, and Hongbin Zhai*. Synthesis of spiro-3H-indazoles via 1,3-dipolar cycloaddition of arynes with 6-diazocyclohex-2-en-1-one derivatives and fused-2H-indazoles by subsequent rearrangement,RSC Advances,2017,7, 54087 – 54090.

(1) Xiaoming Chen,Shengguo Duan, Cheng Tao, Hongbin Zhai*, and Fayang G. Qiu*. Total synthesis of (+)-gelsemine via an organocatalytic Diels-Alder approach,Nature Communication,2015,6, 7204 – 7210.

四、科研项目

五、获奖