段小勇

一、个人简介

段小勇，男，硕士研究生导师，本、硕、博就读于兰州大学化学与化工学院。2016年在兰州大学功能有机分子国家重点实验室获得有机化学专业博士学位，师从韩丙教授，研究方向为自由基化学。2017年3月至2018年3月在新加坡南洋理工大学池永贵教授组从事博士后研究工作，研究方向为不对称有机小分子催化。主要研究方向为自由基化学，不对称催化，有机合成方法学，具有药物活性和生理活性的药物分子合成研究。目前已在该研究方向上发表多篇国际高水平SCI论文。

实验室位于河北大学五四路校区北院逸夫楼715实验室，实验室条件优越，设备齐全，热烈欢迎对有机化学有兴趣的有志人士加入我们团队。

联系方式：duanxy05@126.com

课题组网站：https://www.x-mol.com/groups/Duan_XiaoYong

二、主讲课程及研究方向

1.主讲课程：《有机化学》，《有机化学实验》，《基础有机制备实验》，《综合制备实验》

2.研究方向：自由基化学，不对称催化，有机合成方法学，手性药物分子合成研究。

三、已发表论文

3.Access to dihydropyrano[3,2-b]pyrrol-5-ones skeletons by N-heterocyclic carbene-catalyzed [3+3] annulations.

Ya-Tong Wu, Rui Zhang,Xiao-Yong Duan,*Hai-Fei Yu, Bo-Yu Sun andJing Qi*

Chem. Commun.,2020,56, 9854.

(https://pubs.rsc.org/en/content/articlelanding/2020/CC/D0CC04661B#!divAbstract)

2.N-Heterocyclic Carbene-Catalyzed Activation of Ynals for the Construction of Functional Pyridines

Jia-Hui Li,Xiao-Yong Duan,*Zhao-Hui Tian, Yi-Fan Zheng, andJing Qi*

Asian J. Org. Chem.，2020,9, 385.

(https://onlinelibrary.wiley.com/doi/abs/10.1002/ajoc.201900693)

1.N-Heterocyclic Carbene-Catalyzed [3+2] Cycloaddition of Enals with b,v-Unsaturatedα-Ketumino Esters for the Synthesis of Multisubstituted Cyclopentanone

Xiao-Qian Shi, Meng-Die Dong,Xiao-Yong Duan*,Teng-Liang Cao, andJing Qi*,

Adv. Synth. & Catal.,2020,362, 807.

(https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201901144)

Publications prior joining HBU:

9.Catalytic asymmetric acetalization of carboxylic acids for access to chiral phthalidyl ester prodrugs.
Yingguo Liu, Qiao Chen, Chengli Mou, Lutai Pan,Xiaoyong Duan, Xingkuan Chen, Hongzhong Chen, Yanli Zhao, Yunpeng Lu, Zhichao Jin, Yonggui Robin Chi*
Nature Communications2019,10,1675
（https://www.nature.com/articles/s41467-019-09445-x）

8.Hydrazonyl Radical-Participated Tandem Reaction: A Strategy for the Synthesis of Pyrazoline- Functionalized Oxindoles
Xiao-Yong Duan, Xiu-Long Yang, Pan-Pan Jia, Man Zhang, and Bing Han*
Org. Lett.,2015,17, 6022.
（https://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b03003?journalCode=orlef7&quickLinkVolume=17&quickLinkPage=6022&selectedTab=citation&volume=17）

7.N-heterocyclic carbene-catalyzed stereoselective annulations: An efficient strategy for the synthesis of chromeno [4, 3-b] pyrrolidine derivatives.
Jing Qi*,Xiao-Yong Duan, Li-Li Cao, Wen-Ying Wang
Asian J. Org. Chem.,2015,4, 1254 .
（https://onlinelibrary.wiley.com/doi/10.1002/ajoc.201500266）

6.Transition fromπRadicals toσRadicals: Substituent-Tuned Cyclization of Hydrazonyl Radicals
Xiao-Yong Duan, Neng-Neng Zhou, Ran Fang, Xiu-Long Yang, Wei Yu, and Bing Han*.
Angew. Chem. Int. Ed.,2014,53, 3158 .
（https://onlinelibrary.wiley.com/doi/10.1002/anie.201309918）

5.Hydrazone Radical Promoted Vicinal Difunctionalization of Alkenes and Trifunctionalization of Allyls: Synthesis of Pyrazolines and Tetrahydropyridazines
Xiao-Yong Duan, Xiu-Long Yang, Ran Fang, Xie-Xue Peng, Wei Yu, and Bing Han*
J. Org. Chem.,2013,78, 10692.
（https://pubs.acs.org/doi/abs/10.1021/jo4016908?journalCode=joceah&quickLinkVolume=78&quickLinkPage=10692&selectedTab=citation&volume=78）

4.Oxime Radical Promoted Dioxygenation, Oxyamination, and Diamination of Alkenes: Synthesis of Isoxazolines and Cyclic Nitrones.
Bing Han*, Xiu-Long Yang, Ran Fang, Wei Yu, Chao Wang,Xiao-Yong Duan, Shuai Liu
Angew. Chem. Int. Ed.,2012,51, 8816.
（https://onlinelibrary.wiley.com/doi/10.1002/anie.201203799）

3.Efficient aerobic oxidative synthesis of 2-aryl quinazolines via benzyl C–H bond amination catalyzed by 4-hydroxy-TEMPO
Bing Han*, Chao Wang, Run-Feng Han, Wei Yu,*Xiao-Yong Duan, Ran Fang and Xiu-Long Yang
Chem. Commun.,2011,47, 7818.
（https://pubs.rsc.org/en/content/articlelanding/2011/cc/c1cc12308d#!divAbstract）

2.Efficient aerobic oxidative dehydrogenation of dihydropyrimidinones and dihydropyrimidines
Bing Han*, Run-Feng Han, Yu-Wei Ren,Xiao-Yong Duan, Yi-Chuan Xu, Wei Zhang
Tetrahedron2011,67, 5615.
（https://www.sciencedirect.com/science/article/pii/S0040402011007952）

1.Photoinduced Intramolecular Addition of 3-Acyl-2-haloindoles to Alkenes
Shen-Ci Lu,Xiao-Yong Duan, Zong-Jun Shi, Bing Li, Yu-Wei Ren, Wei Zhang*, Yong-Hui Zhang and Zhi-Feng Tu
Org. Lett.,2009,11, 3902.
（https://pubs.acs.org/doi/abs/10.1021/ol901498f?journalCode=orlef7&quickLinkVolume=11&quickLinkPage=3902&selectedTab=citation&volume=11）

四、科研项目

1.河北大学科研启动资金，2018年至2022年，主持；

2.河北省科技厅青年科学基金项目，2019年9月至2022年8月，主持；

3.河北省教育厅2019年度河北省引进留学人员资助项目,2019年8月至2022年8月，主持;