吴智磊
一、个人简介
吴智磊，男，副教授，硕士研究生导师。2015年6月于天津大学“无机化学”专业获得理学博士学位，师从天津大学崔建中教授，南开大学赵斌教授以及程鹏教授。2016年7月，引进到河北大学化学与环境科学学院工作。主要从事多孔MOFs的设计与合成以及在光、电、磁、催化等性能方面的研究。迄今，已在Angew. Chem. Int. Ed.,Green Chem.,Chem. Eng. J.,J. Catal.,ACS Appl. Mater. Interfaces,Inorg. Chem., Inorg. Chem. Front., Dalton.Trans等国际权威期刊发表学术论文60余篇。先后主持了国家自然科学基金和河北省自然科学基金等多个课题。
联系方式：E-mail: wuzhilei03@163.com;QQ: 491531842
实验室位于逸夫楼719, 115，欢迎本科生和研究生同学加入我们团队共同学习进步。
二、主讲课程及研究方向
1.主讲课程： 现代化学与生活，基础化学实验，综合化学实验
2.研究方向：MOFs的制备及其在光解水、二氧化碳催化、荧光、磁性的应用
三、代表性论文
1. Ai-Ling Gu,Ya-Xin Zhang,Zhi-Lei Wu*, Hui-Ya Cui, Tian-Ding Hu* and Bin Zhao*, Highly Efficient Conversion of Propargylic Alcohols and Propargylic Amines with CO2Activated by Noble-Metal-Free Catalyst Cu2O@ZIF-8,Angew. Chem. Int. Ed.2022,61, e202114817.
2.Zhi-Lei Wu, Chang-Hong Wang, Bin Zhao*, Jie Dong, Feng Lu, Wei-Hua Wang, Wei-Chao Wang*, Guang-Jun Wu, Jian-Zhong Cui and Peng Cheng, A Semi-Conductive Copper–Organic Framework with Two Types of Photocatalytic Activity,Angew. Chem. Int. Ed.2016,55(16), 4938-4942.
3. Cang-Hua Zhang, Tianding Hu, Yu-Ting Zhai, Yaxin Zhang andZhi-Lei Wu*, Stepwise engineering of the pore environment within metal–organic frameworks for green conversion of CO2and propargylic amines,Green Chem.2023, doi.org/10.1039/D2GC04313K.
4.Zhi-Lei Wu, Jian Wang, Shuo Wang*, Ya-Xin Zhang, Guo-Yi Bai*, Luis Ricardez-Sandoval, Gui-Chang Wang* and Bin Zhao, Controllable chemoselective hydrogenation of furfural by PdAg/C bimetallic catalysts under ambient operating conditions: an interesting Ag switch,Green Chem.2020,22, 1432-1442.
5. Hu Li, Chang-Hong Wang, Yu-Fei Xu, Zhao-Zhuo Yu, Shunmugavel Saravanamurugan*,Zhi-Lei Wu*, Song Yang* and Rafael Lugue*, Heterogeneous (de)chlorination-enabled control of reactivity in the liquid-phase synthesis of furanic biofuel from cellulosic feedstock,Green Chem.2020,22, 637–645.
6. Hui-Ya Cui, Ya-Xin Zhang, Chun-Shuai Cao, Tian-Ding Hu*,Zhi-Lei Wu*, Engineering noble-metal-free metal–organic framework composite catalyst for efficient CO2conversion under ambient conditions,Chem. Eng. J.2023,451, 138764.
7.Zhi-Lei Wu, Xingwang Lan*, Ning Gao, Xiaomin Kang, Zhenguang Wang, Tianding Hu*, Bin Zhao*, Highly efficient hydroboration of alkynes catalyzed by porous copper-organic framework under mild conditions,J. Catal.2021,404, 250-257.
8. Cang-Hua Zhang,Zhi-Lei Wu*, Run-Xue Bai,Tianding Hu*, Bin Zhao, Highly Efficient Conversion of Aziridines and CO2Catalyzed by Microporous [Cu12] Nanocages,ACS Appl. Mater. Interfaces2023, 15, 1879−1890.
9. Wen-Min Wang, Wan-Ting Wang, Mei-Ying Wang, Ai-Ling Gu, Tian-Ding Hu*, Ya-Xin Zhang andZhi-Lei Wu*, A Porous Copper−Organic Framework Assembled by [Cu12] Nanocages: Highly Efficient CO2Capture and Chemical Fixation and Theoretical DFT Calculations,Inorg. Chem. 2021,60, 9122−9131.
10. Ai-Ling Gu, Wan-Ting Wang, Xin-Yu Cheng, Tian-Ding Hu*,Zhi-Lei Wu*, Non-Noble-Metal Metal−Organic-Framework-Catalyzed Carboxylative Cyclization of Propargylic Amines with Atmospheric Carbon Dioxide under Ambient Conditions,Inorg. Chem.2021,60, 13425−13433.
11.Zhi-Lei Wu, Ai-Ling Gu, Ning Gao, Hui-Ya Cui, Wen-Min Wang*, and Jian-Zhong Cui*, Solvent-Dependent Assembly and Magnetic Relaxation Behaviors of [Cu4I3] Cluster-Based Lanthanide MOFs: Acting as Efficient Catalysts for Carbon Dioxide Conversion with Propargylic Alcohols,Inorg. Chem. 2020,59, 15111−15119.
12. Wen-Min Wang, Xiao-Yan Xin, Na Qiao,Zhi-Lei Wu*, Ling Li, Ji-Yong Zou*, Self-assembly of octanuclear Ln(III)-based clusters: their large magnetocaloric effects and highly efficient conversion of CO2,Dalton Trans.2022,51, 13957.
13. Wen-Min Wang,Zhi-Lei Wu* and Jian-Zhong Cui*, Molecular assemblies from linear-shaped Ln4 clusters to Ln8 clusters using different β-diketonates: disparate magnetocaloric effects and single-molecule magnet behaviours,Dalton Trans., 2021,50, 12931-12943.
14.Zhi-Lei Wu, Xin-Wang Lan*, Ya-Xin Zhang, Meng Li and Guo-Yi Bai*, Copper(I) iodide cluster-based lanthanide organic frameworks: synthesis and application as efficient catalysts for carboxylative cyclization of propargyl alcohols with CO2under mild conditions,Dalton Trans.2019,48(29), 11063–11069.
15. Wen-Min Wang, Li-Yuan He, Xin-Xin Wang, Ying Shi,Zhi-Lei Wu* and Jian-Zhong Cui*, Linear-shaped LnIII4and LnIII6clusters constructed by polydentate Schiff base ligand and β-diketone co-ligand: structures, luminescence properties, magnetic refrigeration and single-molecule magnet behavior,Dalton Trans.2019,48(44), 16744–16755.
16. Wen-Min Wang,Zhi-Lei Wu*, Ya-Xin Zhang, Hai-Ying Wei, Hong-Ling Gao and Jian-Zhong Cui*, Self-assembly of tetra-nuclear lanthanide clusters via atmospheric CO2fixation: interesting solvent-induced structures and magnetic relaxation conversions,Inorg. Chem. Front.2018,5(9), 2346-2354.
17. Wen-Min Wang, Xiao-Min Kang, Hai-Yun Shen,Zhi-Lei Wu*, Hong-Ling Gao, Jian-Zhong Cui*, Modulating single-molecule magnet behavior towards multiple magnetic relaxation processes through structural variation in Dy4clusters,Inorg. Chem. Front.2018,5(8), 1876-1885.
18.Zhi-Lei Wu, Jie Dong, Wei-Yan Ni, Bo-Wen Zhang, Jian-Zhong Cui and Bin Zhao*, Unique Chiral Interpenetrating d−f Heterometallic MOFs as Luminescent Sensors,Inorg. Chem.2015,54(11), 5266−5272.
四、科研项目
1.基于芳香多羧酸配体的光解水制氢MOFs催化剂的可控构筑及性能研究(项目编号：21701039)，国家自然科学青年基金（2018-2020年，主持人）
2.用于光解水制氢的MOFs基光催化剂的设计、合成及性能研究（项目编号：B2017201055），河北省自然科学青年基金（2017-2019年，主持人）
