一、个人简介
杨修龙,男,博士,校聘教授,硕士生导师。2015年6月毕业于兰州大学有机化学专业,获得博士学位,导师为韩丙教授。2016年2月至于2020年9月加入中国科学院理化技术研究所吴骊珠院士课题组从事有机光化学博士后研究工作。2021年1月入职河北大学,任校聘教授,从事教学和科研工作。至今为止,以第一(含共同第一)/通讯作者在Angew. Chem. Int. Ed., Org. Lett., J. Org. Chem.等期刊上发表研究论文12篇。目前主持国家自然科学基金青年基金、河北省自然科学基金青年基金和河北大学高层次引进人才项目3项。
联系方式:yangxl@hbu.edu.cn, D5-516实验室。
ORCID iD: https://orcid.org/0000-0003-3933-7738
热忱欢迎优秀的研究生和本科生加入课题组学习和发展!
二、研究方向
1. 基于电子转移/能量传递途径的有机光化学转化。
2. 物理有机化学对自由基产生及其化学选择性的指导。
3. 新型光功能有机分子的结构设计、合成及其性质研究。
三、代表性论文
12. Hao-Yuan Li, Xiaoying Niu* and Xiu-Long Yang*, Photoinduced Generation of Active Intermediates from Unmodified 1,3-Dicarbonyl Compounds for Organic Transformations. Eur. J. Org. Chem. 2024, DOI: 10.1002/ejoc.202400102.
11. Jun-Li Li, Xiaoying Niu,* Yi-Fan Song, Jian-Long Du, Shigang Shen* and Xiu-Long Yang*, Photocatalytic synthesis of 10-phenanthrenols via intramolecular cycloaromatization under oxidant-free conditions. Org. Chem. Front., 2022, 9, 6156–6164.
10. Yi-Fan Song, Xiaoying Niu,* Jincan Zhao, Shigang Shen and Xiu-Long Yang*,Visible-light-mediated defluorinative cyclization of α-fluoro-β-enamino esters catalyzed by 4-CzIPN. Org. Chem. Front. 2022, 9, 3499–3505.
9. Xiu-Long Yang, Jia-Dong Guo, Tao Lei, Bin Chen, Chen-Ho Tung, and Li-Zhu Wu*, Photoredox Catalysis of Aromatic β-Ketoester for in Situ Production of Transient and Persistent Radicals for Organic Transformation. Angew. Chem. Int. Ed. 2020, 59, 5365-5370.
8. Jia-Dong Guo†, Xiu-Long Yang†, Bin Chen, Chen-Ho Tung, Li-Zhu Wu*, Photoredox/Cobalt-Catalyzed C(sp3)–H Bond Functionalization toward Phenanthrene Skeletons with Hydrogen Evolution. Org. Lett. 2020, 22, 9627-9632. (†Contributed equally)
7. Xiu-Long Yang, Jia-Dong Guo, Tao Lei, Bin Chen, Chen-Ho Tung, and Li-Zhu Wu*, Oxidative Cyclization Synthesis of Tetrahydroquinolines and Reductive Hydrogenation of Maleimides under Redox-Neutral Conditions. Org. Lett. 2018, 20, 2916-2920.
6. Xiu-Long Yang, Qing-Yuan Meng, Xue-Wang Gao, Tao Lei, Cheng-Juan Wu, Bin Chen, Chen-Ho Tung, and Li-Zhu Wu*, Superoxide Radical Anion-Mediated Aerobic Oxidative Synthesis of 2-Substituted Quinazolines under Visible Light, Asian J. Org. Chem. 2017, 6, 449-452.
5. Xiu-Long Yang, Xie-Xue Peng, Fei Chen, and Bing Han*, TEMPO-Mediated Aza-Diels–Alder Reaction: Synthesis of Tetrahydropyridazines Using Ketohydrazones and Olefins. Org. Lett. 2016, 18, 2070-2073.
4. Xiu-Long Yang, Yan Long, Fei Chen, and Bing Han*, Synthesis of Isoxazoline-featured Oxindoles by Iminoxyl Radical-promoted Cascade Oxyalkylation/alkylarylation of Alkenes. Org. Chem. Front. 2016, 3, 184-189.
3. Xiu-Long Yang, Fei Chen, Neng-Neng Zhou, Wei Yu, and Bing Han*, Synthesis of Isoxazoline-Functionalized Phenanthridines via Iminoxyl Radical-Participated Cascade Sequence. Org. Lett. 2014, 16, 6476-6479.
2. Bing Han*, Xiu-Long Yang, Ran Fang, Wei Yu, Chao Wang, Xiao-Yong Duan, and Shuai Liu, Oxime Radical Promoted Dioxygenation, Oxyamination, and Diamination of Alkenes: Synthesis of Isoxazolines and Cyclic Nitrones. Angew. Chem. Int. Ed. 2012, 51, 8816-8820.
1. Bing Han*, Xiu-Long Yang, Chao Wang, Yong-Wei Bai, Tai-Chao Pan, Xin Chen, and Wei Yu*, CuCl/DABCO/4-HO-TEMPO-Catalyzed Aerobic Oxidative Synthesis of 2-Substituted Quinazolines and 4H-3,1-Benzoxazines. J. Org. Chem. 2012, 77, 1136-1142.
四、科研项目
1. 国家自然科学基金青年项目(No 22101070),2022.01-2024.12,主持。
2. 河北省自然科学基金青年项目(No B2021201015),2021.01-2023.12,主持。
3. 河北大学高层次人才科研启动项目, 2021.03-2023.12,主持。